Insight into the chemoselective aromatic <i>vs.</i> side-chain hydroxylation of alkylaromatics with H₂O₂ catalyzed by a non-heme imine-based iron complex

Computational Insight into the Alkane- Hydroxylation Mechanism by Non-Heme Fe(PyTACN) Iron Complexes. Effect of the Substrate and Solvent

Mechanistic insight into halide oxidation by non-heme iron complexes. Haloperoxidase versus halogenase activity.

This work presents the first detailed study on mechanistic aspects of halide oxidation by non-heme iron complexes. We show that while iron(III)-hydroperoxo complexes oxidise halides via oxygen atom transfer, the corresponding iron(IV)-oxo complex reacts via electron transfer.

Regioselectivity of aliphatic versus aromatic hydroxylation by a nonheme iron(II)-superoxo complex.

Many enzymes in nature utilize molecular oxygen on an iron center for the catalysis of substrate hydroxylation. In recent years, great progress has been made in understanding the function and properties of iron(IV)-oxo complexes; however, little is known about the reactivity of iron(II)-superoxo intermediates in substrate activation. It has been proposed recently that iron(II)-superoxo intermed...

a corpus-based study of the frequency of personal pronouns in translated and comparable non-translated persian texts

چکیده ندارد.

Ortho-hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center.

The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where is [Fe(II)(BPMEN)(CH3CN)2](ClO4)2 and BPMEN =N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononuclear iron(III) complex with a chelating salicylate.